editedbook
Publication: IIP Proceedings Year: 2022, Month: November Page No: 233-243, ISSN/ISBN: 978-93-95632-67-6, DOI/Link: https://www.rsquarel.org/assets/docupload/rsl2023B5D8BE4381ACB7F.pdf
CONTEMPORARY TRENDS IN THE SYNTHETIC ASPECTS, AND MAGNETIC PROPERTIES OF 3d-4f HETEROMETALLIC CUBANE, PARTIAL DICUBANE, AND PARTIAL TETRACUBANE CORE-TYPE COORDINATION COMPOUNDS
Area/Stream: Chemical, Material Sciences & Nano Technology, Authors: Bilash Chandra Roy, Dr. Tufan Singha Mahapatra Keywords: Synthetic aspects, magnetic properties heterometallic cubane, tetra cubane Book Name /series: Futuristic Trends in Chemical, Material Sciences & Nano Technology, Volume 2, Book 13, Part 4, Chapter 1Publication: IIP Proceedings Year: 2022, Month: November Page No: 233-243, ISSN/ISBN: 978-93-95632-67-6, DOI/Link: https://www.rsquarel.org/assets/docupload/rsl2023B5D8BE4381ACB7F.pdf
Abstract:
Over the past two to three decades, the synthesis of multinuclear 3d-4f complexes acquired significant interest because of their fascinating topological structures, and intriguing properties in several areas, such as catalysis, magnetic materials, luminescent materials, and biomaterials. Compartmental ligands like Schiff bases are useful candidates in the manufacture of 3d-4f heterometallic multinuclear complexes as different coordination sites available for different metals. 4f ions like Eu(III), Dy(III), Tb(III), and Ho(III) are hard and oxophilic and preferentially interact with the oxygen-rich parts of ligands, while 3d ions like Mn(II/III), Fe(II), Ni(II), Cu(II) are soft in comparison and prefer nitrogen atoms for binding. Lanthanide (III) ions are regarded as potential building blocks for new types of magnetic materials due to their large magnetic anisotropy, which arises due to large spin-orbit coupling interactions. In this book chapter, we have discussed the synthetic aspects, and magnetic properties of 3d–4f coordination compounds with cubane, partial dicubane, and partial tetracubane cores.
Cite this: Bilash Chandra Roy, Dr. Tufan Singha Mahapatra,"CONTEMPORARY TRENDS IN THE SYNTHETIC ASPECTS, AND MAGNETIC PROPERTIES OF 3d-4f HETEROMETALLIC CUBANE, PARTIAL DICUBANE, AND PARTIAL TETRACUBANE CORE-TYPE COORDINATION COMPOUNDS", Futuristic Trends in Chemical, Material Sciences & Nano Technology, Volume 2, Book 13, Part 4, Chapter 1, November, 2022, 233-243, 978-93-95632-67-6, https://www.rsquarel.org/assets/docupload/rsl2023B5D8BE4381ACB7F.pdf
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